
76. The
correct statements from following are:
A. The strength of anionic ligands can be
explained by crystal field theory.
B. Valence bond theory does not give a
quantitative interpretation of kinetic stability of
coordination compounds.
C. The hybridization involved in formation of
[Ni(CN)4]2–complex is dsp2.
D. The number of possible isomer(s) of
cis-[PtC12 (en)2]2+ is one
Choose the correct answer from the options given
below:
(1) A, D only
(2) A, C only
(3) B, D only
(4) B, C only
Ans. (4)
Sol. B. VBT does not explain stability of complex
C. Hybridisation of [Ni(CN)4]–2 is dsp2.
77. The linear combination of atomic orbitals to form
molecular orbitals takes place only when the
combining atomic orbitals
A. have the same energy
B. have the minimum overlap
C. have same symmetry about the molecular axis
D. have different symmetry about the molecular
axis
Choose the most appropriate from the options
given below:
(1) A, B, C only
(2) A and C only
(3) B, C, D only
(4) B and D only
Ans. (2)
Sol. * Molecular orbital should have maximum overlap
* Symmetry about the molecular axis should be
similar
78. Match List I with List II
LIST-I LIST-II
A.
Glucose/NaHCO3/D I. Gluconic acid
B. Glucose/HNO3 II. No reaction
C. Glucose/HI/ D III. n-hexane
D.
Glucose/Bromine
water]
IV. Saccharic acid
Choose the correct answer from the options given
below:
(1) A-IV, B-I, C-III, D-II
(2) A-II, B-IV, C-III, D-I
(3) A-III, B-II, C-I, D-IV
(4) A-I, B-IV, C-III, D-II
Ans. (2)
Sol. Glucose 3
NaHCO
D
no reaction
Glucose 3
HNO
D
saccharic acid
Glucose HI
D
n-hexane
Glucose 2
Br
D
Gluconic acid
79. Consider the oxides of group 14 elements
SiO2, GeO2, SnO2, PbO2, CO and GeO. The
amphoteric oxides are
(1) GeO, GeO2
(2) SiO2, GeO2
(3) SnO2, PbO2
(4) SnO2, CO
Ans. (3)
Sol. SnO2 and PbO2 are amphoteric
80. Match List I with List II
LIST I (Technique) LIST II (Application)
A. Distillation I. Separation of
glycerol from
spent-lye
B. Fractional
distillation
II. Aniline - Water
mixture
C. Steam
distillation
III. Separation of crude
oil fractions
D. Distillation
under reduced
pressure
IV. Chloroform-
Aniline
Choose the correct answer from the options given below:
(1) A-IV, B-I, C-II, D-III
(2) A-IV, B-III, C-II. D-I
(3) A-I. B-II, C-IV, D-III
(4) A-II, B-III. C-I, D-IV
Ans. (2)
Sol. Fact (NCERT)