
Sol:- (A) All group 16 elements form oxides of the
type where
.
(B)
is reducing while
is an oxidising
agent.
(C) The reducing property increases from
to
down the group.
(D)
O
.. O
O
. .
..
..
..
..
have six lone pairs
73. Identify the name reaction.
CO, HCl CHO
Anhyd. AlCl /CuCl
3
(1) Stephen reaction
(2) Etard reaction
(3) Gatterman-koch reaction
(4) Rosenmund reduction
Ans. (3)
Sol:-
CO, HCl CHO
Anhyd. AlCl /CuCl
3
Gatterman-Koch reaction
74. Which of the following is least ionic ?
(1)
(2) AgCl
(3) KCl (4)
Ans. (2)
Sol:-
22
AgCl CoCl BaCl KCl
(ionic character)
Reason :
has pseudo inert gas configuration.
75. The fragrance of flowers is due to the presence of
some steam volatile organic compounds called
essential oils. These are generally insoluble in
water at room temperature but are miscible with
water vapour in vapour phase. A suitable method
for the extraction of these oils from the flowers is -
1. crystallisation
2. distillation under reduced pressure
3. distillation
4. steam distillation
Ans. (4)
Sol:- Steam distillation technique is applied to separate
substances which are steam volatile and are
immiscible with water.
76. Given below are two statements :
Statement I: Group 13 trivalent halides get easily
hydrolyzed by water due to their covalent nature.
Statement II:
upon hydrolysis in acidified
aqueous solution forms octahedral
ion.
In the light of the above statements, choose the
correct answer from the options given below :
1. Statement I is true but statement II is false
2. Statement I is false but statement II is true
3. Both statement I and statement II are false
4. Both statement I and statement II are true
Ans. (4)
Sol:- In trivalent state most of the compounds being
covalent are hydrolysed in water. Trichlorides on
hydrolysis in water form tetrahedral
species, the hybridisation state of element M is
In case of aluminium, acidified aqueous solution
forms octahedral
ion.
77. The four quantum numbers for the electron in the
outer most orbital of potassium (atomic no. 19) are
(1)
= 2,
(2)
= 0,
,
(3)
= 0,
,
(4)
,
= 0,
,
Ans. (2)
Sol:-
2 2 6 2 6 1
1s , 2s , 2p , 3s , 3p , 4s
.
Outermost orbital of potassium is 4s orbital
l1
n 4, l 0, m 0, s 2
.