
79. Given below are two statements:
Statement I: Fluorine has most negative electron
gain enthalpy in its group.
Statement II: Oxygen has least negative electron
gain enthalpy in its group.
In the light of the above statements, choose the
most appropriate from the options given below.
(1) Both Statement I and Statement II are true
(2) Statement I is true but Statement II is false
(3) Both Statement I and Statement II are false
(4) Statement I is false but Statement II is true
Ans. (4)
Sol. Statement-1 is false because chlorine has most
negative electron gain enthalpy in its group.
80. Anomalous behaviour of oxygen is due to its
(1) Large size and high electronegativity
(2) Small size and low electronegativity
(3) Small size and high electronegativity
(4) Large size and low electronegativity
Ans. (3)
Sol. Fact Based.
SECTION-B
81. The total number of anti bonding molecular
orbitals, formed from 2s and 2p atomic orbitals in a
diatomic molecule is _____________.
Ans. (4)
Sol. Antibonding molecular orbital from 2s = 1
Antibonding molecular orbital from 2p = 3
Total = 4
82. The oxidation number of iron in the compound
formed during brown ring test for
ion is _____.
Ans. (1)
Sol. [Fe(H2O)5(NO)]2+,
Oxidation no. of Fe = +1
83. The following concentrations were observed at
500 K for the formation of NH3 from N2 and H2. At
equilibrium :[N2] = 2 × 10–2 M, [H2] = 3 ×10–2 M and
[NH3] = 1.5 ×10–2M. Equilibrium constant for the
reaction is _______.
Ans. (417)
Sol.
2
2
C3
22
1.5 10
K2 10 3 10
KC = 417
84. Molality of 0.8 M H2SO4 solution (density 1.06 g cm–3)
is _____×10–3 m.
Ans. (815)
Sol.
sol solute
M 1000
md 1000 M Molar mass
815 × 10–3 m
85. If 50 mL of 0.5 M oxalic acid is required to
neutralise 25 mL of NaOH solution, the amount of
NaOH in 50 mL of given NaOH solution is
_____g.
Ans. (4)
Sol. Equivalent of Oxalic acid = Equivalents of NaOH
50 × 0.5 × 2 = 25 × M × 1
MNaOH = 2M
WNaOH in 50ml = 2 × 50 × 40 × 10–3 g = 4g
86. The total number of ‘Sigma’ and Pi bonds in 2-
formylhex-4-enoic acid is ____.
Ans. (22)
Sol.
C C C C C C
C
O
H
OH H
O HH
H
HHHH
22 bonds
87. The half-life of radioisotopic bromine - 82 is 36
hours. The fraction which remains after one day is
___________ ×10–2.
(Given antilog 0.2006 = 1.587)
Ans. (63)
Sol. Half life of bromine – 82 = 36 hours
= 0.01925 hr–1
1st order rxn kinetic equation
(t = 1day = 24hr)
1
a 24hr 0.01925hr
log a x 2.303
If a = 1
1 – x = 0.6301 = Fraction remain
after one day